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According to Washington Business Journal, "The first communities to receive access to Verizon FiOS service will be Barry Farm, Brightwood, Cleveland Park, Crestwood, Fort Stanton, Friendship Heights, Historic Anacostia, Petworth, Shepherd Park, Sheridan, Tenleytown, Van Ness and Woodley Park."
I'm guessing Mount Pleasant and other neighborhoods on the 42 will have to wait a bit due to construction. Fiber optic cables and other hardware will literally have to be laid underground for the upgrade to happen. Delivery of the service is due sometime in 2009.